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This work are among basic science which gives young researchers basics and knowledge of analysis related to glassy structure using an important, available and non-destructive tool for structure determination (FTIR)supported by a new theoretical method(DFT). The work starts with a short survey and available theories in glass structure and extended for the study of various type of glasses; from binary, ternary and quarterly in their composition, Silicate, borate, phosphate and mixed former in their constituent, flat, and bioglass in different applications.